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Inhalation Remove to fresh air. Methylene chloride is highly volatile with a low boiling point (104°F) and vapor pressure (350mm Hg). Source Products By Show Name: PRODUCT AND COMPANY IDENTIFICATION Product Name: Methylene Chloride Synonyms/Generic Names: Dichloromethane Product Number: NC-11527, NC-9025, 5409 Product Use: Industrial, Manufacturing or Laboratory use Distributor: Science Company 7625 W Hampden Ave #14 Lakewood CO 80227 Specifically, “In classifying the hazards of methylene chloride at least the following hazards are to be addressed: Cancer, cardiac effects (including elevation of carboxyhemoglobin), central nervous system effects, liver effects, and skin and eye irritation.” 1910.1052(k)(1)(ii) Methylene chloride is used in various industrial processes, in many different industries including paint stripping, pharmaceutical manufacturing, paint remover manufacturing, and metal cleaning and degreasing. The symptoms are the same as from other sources of carbon monoxide : nausea, vomiting, headache, drowsiness, coma, … Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or cardiovascular function may be more susceptible to the effects of this substance. In four human subjects exposed to methylene chloride (350 mg/cu m) for 2 hr, an average of 22.6 microg methylene chloride was excreted in the urine within 24 hr after the exposure. METHYLENE CHLORIDE _____ SDS No. Methylene chloride is metabolically converted to carbon monoxide after systemic absorption, which yields increased concentrations of carboxyhemoglobin in the blood. This chemical is widely used in consumer products, yet without appropriate protections, exposure may lead to death. OSHA considers methylene chloride to be a potential occupational carcinogen. F (20 deg. Methylene chloride is a solvent which is used in many different types of work activities, such as paint stripping, polyurethane foam manufacturing, cleaning, and degreasing. [Note: A gas above 104°F.] Exposures to methylene chloride are addressed in specific OSHA standards for general industry, maritime, and construction. If not breathing, give artificial respiration. A common synonym for methylene chloride is dichloromethane. Methylene chloride (dichloromethane) is a widely used solvent that can cause serious illness or death when used in enclosed spaces. Methylene chloride is used in various industrial processes, in many different industries including paint stripping, pharmaceutical manufacturing, paint remover manufacturing, and metal cleaning and degreasing. Already banned in some countries, the Environmental Protection Agency (EPA) recently proposed limiting its use in the United States. Provides links and references to additional resources related to exposures to methylene chloride. Causes eye, skin, and respiratory tract irritation. Overexposure to methylene chloride can cause both immediate and long-term health effects. SAFETY DATA SHEET Methylene Blue According to Regulation (EC) No 1907/2006, Annex II, as amended. Potential cancer hazard. CDC - NIOSH Pocket Guide to Chemical Hazards - Methylene chloride Causes eye, skin, and respiratory tract irritation. Methylene Chloride: Hazards. May be harmful if inhaled. A window was partially open for ventilation. By National Institute for Occupational Safety and Health. Provides references that may aid in evaluating methylene chloride exposures in the workplace. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Hazard alert | Methylene chloride hazards for bathtub refinishers (OSHA/NIOSH) Methylene chloride can be particularly dangerous when used in small rooms with no ventilation. The hazard alert, part of OSHA’s Fatal Facts series, states that the temporary worker was using a common paint stripper to remove bathtub coating in a small bathroom in an apartment building. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in … The Workplace Safety and Health Branch has recently dealt with a serious workplace incident involving a product containing the chemical methylene chloride (CAS 75-09-2). Page 2 of 7 MSDS ± Methylene Chloride Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog. The msds of methylene chloride products are most popular in India, Pakistan, Vietnam, Indonesia, Brazil, Russia, Mexico, United States, Turkey, Germany, etc. If swallowed or ingested, this material may pose an aspiration hazard Physical Hazards Not Otherwise Classified • Not Classified Health Hazards Not Otherwise Classified • Methylene chloride can be metabolized to carbon monoxide (CO), which is then very tightly bound to hemoglobin. Methylene chloride is metabolically converted to carbon monoxide after systemic absorption, which yields increased concentrations of carboxyhemoglobin in the blood. Related NIOSH Resources. : M47008 Rev. Methylene chloride may cause cancer in humans. Potential cancer hazard. May cause central nervous system effects. EPA has a Methylene Chloride Hazard Summary. Methylene chloride is converted to carbon monoxide in the body, which reduces the oxygen carrying capacity of the ... 5.2 Special hazards arising from the substance or mixture Explosive mixtures of methylene chloride and air can be formed, but are difficult to ignite and require high intensity sources of Inflammation of the eye is characterized by redness, watering, and itching. HAZARDS IDENTIFICATION Health Hazards Acute & Chronic: Inhalation: Methylene chloride depresses the central nervous system. Methylene chloride form carbon monoxide in the body. Booklet | Methylene chloride (OSHA) [PDF] A booklet including standards, monitoring, exposures, protection, and training. This chemical/product is not and cannot be distributed in commerce (as What are the hazards associated with methylene chloride? 75 -09 -2 Methylene chloride >99.5 200 -838-9 Hazard Symbols: XN Risk Phrases: 40 Section 3 - Hazards Identification EMERGENCY OVERVIEW Limited evidence of a carcinogenic effect. ; Proposition 65 requires businesses to determine if they must provide a warning about exposures to listed chemicals. Closed containers exposed to heat may explode. The primary exposure route for methylene chloride is via inhalation, although absorption through the skin is also a concern. May cause kidney damage. Provides resources that contain information to help control exposures. NIOSHTIC-2 search results on methylene chloride—NIOSHTIC-2 is a searchable database of worker safety and health publications, documents, grant reports, and journal articles supported in whole or in part by NIOSH. SAFETY DATA SHEET Methylene Chloride (298, 299, 300) 000000011394 Version 1.3 3 Revision Date 10/04/2017 Print Date 11/16/2017 3/13 4. Methylene Chloride Hazards for Bathtub Refinishers An overview of the effects of methylene chloride in bathtub stripping products. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Booklet | Methylene chloride (OSHA) [PDF] A booklet including standards, … safety hazards of Methyl Chloride to potentially exposed workers. If your workers use methylene chloride on the job, they may be exposed to the chemical through inhalation, absorption through the skin, or skin contact. Potential Acute Health Effects: Very hazardous in case of eye contact (irritant), of ingestion, of inhalation. Methylene chloride (CH 2 Cl 2) is a colorless liquid that can harm the eyes, skin, liver, and heart. In seven subjects exposed to 710 mg/cu m for 2 hr, the corresponding value was 81.5 ug. These effects can result from inhalation or dermal exposure to methylene chloride. You can ensure product safety from certified suppliers certified to the relevant standards. Potential Hazards: Methylene chloride/dichloromethane exposure can cause central nervous system, liver, and cardiovascular effects. Dichloromethane (Methylene Chloride) Hazards & Safety Information Feb 20, 2015 Dichloromethane (also commonly known as Methylene Chloride, Methylene Dichloride, Di-clo and DCM) is a clear, slightly sweet smelling organic liquid chemical solvent which can be pose significant workplace safety risks if strict handling instructions are not followed. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Methylene chloride is a poison and may be fatal if swallowed. In the body, methylene chloride is converted to carbon monoxide. Washington – OSHA is warning workers of the dangers of methylene chloride after a temporary worker died from exposure to the chemical. It is metabolized by the body to carbon monoxide, and can affect the blood’s ability to transport oxygen. Hazard classification & labelling Hazard classification and labelling. Methylene chloride is a solvent which is used in many different types of work activities, such as paint stripping, polyurethane foam manufacturing, cleaning, and degreasing. Potential Health Effects Eye: Contact with eyes may cause severe irritation, and p ossible eye burns. Inhalation Remove to fresh air. Occupational Safety & Health Administration, Occupational Safety and Health Administration, Lethal Exposure to Methylene Chloride during Bathtub Refinishing, Preventing Worker Deaths from Paint Strippers Containing Methylene Chloride, Methylene Chloride Hazards for Bathtub Refinisher, Review of OSHA's Methylene Chloride standard shows value to worker protection, Notice of Availability of the Regulatory Flexibility Act Review of the Methylene Chloride Standard, Severe Storm and Flood Recovery Assistance. Transport information DOT UN-No UN1593 Proper Shipping Name DICHLOROMETHANE Hazard Class 6.1 Packing Group III TDG UN-No UN1593 Proper Shipping Name DICHLOROMETHANE Hazard Class 6.1 Packing Group III IATA UN-No UN1593 _____ Page 6 / 8 The information in CAMEO Chemicals comes from a variety of data sources. Name: Methylene Chloride Synonyms: dichloromethane; methylene dichloride; methylene bichloride CAS# 75-09-2 Product Uses: Uses Advised Against: Cleaning solvent, paint stripper, refrigeration heat transfer fluid. Use oxygen as required, provided a qualified operator is present. Methylene chloride Revision Date 28-November-2019 Component RCRA - U Series Wastes RCRA - P Series Wastes Methylene chloride - 75-09-2 U080 - 14. Methylene chloride. Skin: May be absorbed through the skin. Product identifier Product name Methylene Blue Product number PL.7027, PL.7027/25, PL.7027/100, PL.7028, PL.7029 1.2. Flammable Properties: Can ignite if strongly heated. Methylene chloride is removed from the body mainly in expired air and urine. Severe exposure can cause loss of consciousness and death. It’s much better than chloroform because of the following adventages: – it is less harmful – it has less penetrating odor – rinsing of gutta-percha oddments is easier The information in CAMEO Chemicals comes from a variety of data sources. If skin irritation persists, call a physician. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Hazardous in case of skin contact (irritant, permeator). (1,6) The chemical formula for methylene chloride is CH 2 Cl 2, and the molecular weight is 84.93 g/mol. Methylene Chloride ACS Safety Data Sheet 1. Date: 24-Jul-2019 Supersedes Date: 08-Apr-2019 • Methylene chloride can be metabolized to carbon monoxide (CO), which is then very tightly bound to hemoglobin. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Dichloromethane OTHER/GENERIC NAMES: Methylene Chloride, Methylene Dichloride, DCM, MC PRODUCT USE: Solvent MANUFACTURER: Honeywell 1953 South Harvey Street Exposure to methylene chloride may increase the risk of cancer. (1,6) The chemical formula for methylene chloride is CH 2 Cl 2, and the molecular weight is 84.93 g/mol. This substance has caused adverse reproductive and fetal effects in animals. If breathing is difficult, give oxygen. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. It is metabolized by the body to carbon monoxide, and can affect the blood’s ability to transport oxygen. OSHA Vacated PELs: Methylene Blue: No OSHA Vacated PELs are listed for this chemical. Methylene chloride is an industrial solvent used in commercial paint strippers and degreasing agents. If skin irritation persists, call a physician. Synonyms : 3,7-bis(dimethylamino)phenazathionium chloride / 3,9-bis(dimethylamino)phenazothioniumchloride / aizen methylene blue / basic blue 9 / basic lake blue / C.I.52015 / calcozine blue ZF / chromosmon / D and C blue number 1 / duasyn basic blue IAD / external blue 1 / hidaco methylene blue salt free / leather pure blue HB / methylene Harmful if swallowed. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or cardiovascular function may be more susceptible to the effects of this substance. (1,4) Methylene chloride is a colorless liquid with a sweetish odor. What are fire hazards and extinguishing media for methylene chloride? Potential Hazards: Methylene chloride/dichloromethane exposure can cause central nervous system, liver, and cardiovascular effects. Dichloromethane, Methylene dichloride Colorless liquid with a chloroform-like odor. Washington – OSHA is warning workers of the dangers of methylene chloride after a temporary worker died from exposure to the chemical. Methylene Chloride: Hazards If your workers use methylene chloride on the job, they may be exposed to the chemical through inhalation, absorption through the skin, or skin contact. Methylene chloride is used in endodontics as a very efficient dissolving agent of gutta-percha and endomethasone. Material Safety Data Sheet Dichloromethane MSDS Number: BDH-120 Page 1 of 9 1. methylene chloride msds, US $ 480 - 580 / Metric Ton, CHLORIDE, Methylene Chloride, Methylene Chloride, 75-09-2.Source from Zhengzhou Sino Chemical Co., Ltd. on Alibaba.com. Already banned in some countries, the Environmental Protection Agency (EPA) recently proposed limiting its use in the United States. Methylene chloride Revision Date 28-Nov-2019 Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Employees exposed to methylene chloride are at increased risk of developing cancer, adverse effects on the heart, central nervous system and liver, and skin or eye irritation. Methylene Chloride Hazards for Bathtub Refinishers An overview of the effects of methylene chloride in bathtub stripping products. Occupational Safety & Health Administration, Occupational Safety and Health Administration, Criteria for a Recommended Standard: Occupational Exposure to Methylene Chloride, International Agency for Research on Cancer (IARC) Monographs on the Evaluation of Carcinogenic Risks for Humans, Toxicological Profile for Methylene Chloride, International Chemical Safety Cards (ICSC), Severe Storm and Flood Recovery Assistance. The hazard alert, part of OSHA’s Fatal Facts series, states that the temporary worker was using a common paint stripper to remove bathtub coating in a small bathroom in an apartment building. Material Safety Data Sheet Dichloromethane MSDS Number: BDH-120 Page 1 of 9 1. This complex is called carboxyhemoglobin (COHb) and results in a reduction in the oxygen carrying capacity of the blood. It has a boiling point of 104 deg. F and a vapor pressure of 350 mm at 68 deg. Skin Contact: SKIN IRRITANT. Overexposure to methylene chloride can cause both immediate and long-term health effects. May be harmful if inhaled. It may cause cancer. The video was produced by the California Fatality Assessment and Control Evaluation (FACE) within the Occupational Health Branch of … In February 2012, a worker using a product containing methylene chloride to refinish a bathtub was found dead, slumped over a bathtub in an unventilated bathroom. Methylene chloride is a volatile, colorless liquid that has a chloroform-like odor. The most common means of exposure to methylene chloride is inhalation and skin exposure. Due to its high vapor pressure, methylene chloride can act as a simple asphyxiant by displacing air. Target Organs: Blood, central ne… OSHA Vacated PELs: Methylene Blue: No OSHA Vacated PELs are listed for this chemical. METHYL CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. A common synonym for methylene chloride is dichloromethane. The principal hazards associated with occupational exposure to methylene chloride are the health effects it produces. Skin: prolonged or repeated contact may cause irritation, defatting of skin & dermatitis. Methylene chloride hazards for bathtub refinishers . The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Methylene chloride, also called dichloromethane, is a volatile, colorless liquid with a chloroform-like odor. Employees exposed to methylene chloride are at increased risk of developing cancer, adverse effects on the heart, central nervous system and liver, and skin or eye irritation. Methylene chloride may cause cancer in humans. Causes moderate to severe irritation. Get medical attention. If you breathe methylene chloride at concentrations of 300 parts per million (ppm) or greater for a short period of time (3-4 hours) you may not be able to hear faint sounds and your vision may be slightly impaired. The primary routes of exposure to methylene chloride are by inhalation and direct contact with the skin and eyes. Harmful if swallowed. Methylene chloride is incompatible with alkali metals, strong oxidizing agents, strong bases, and oxides of nitrogen, zinc, aluminum, water, magnesium, and amines. Methylene chloride poisoning incidents during paint stripping operations and bath tub refinishing have demonstrated that inhalation exposure at extremely high levels can be fatal to humans. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in … This chemical is widely used in consumer products, yet without appropriate protections, exposure may lead to death. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Combined with its heavier-than-air molecular weight (85), methylene chloride is a serious inhalation hazard. Handling Guidelines for Minimizing Worker Exposure Exposure can cause drowsiness, dizziness, numbness and tingling limbs, and nausea. Get medical attention. If not breathing, give artificial respiration. If not breathing, give artificial respiration. States that operate their own occupational safety and health programs approved by Federal OSHA enforce similar standards but may have different or additional requirements. Methylene chloride - 75-09-2 U080 - 14. Methylene chloride is irritating to the skin, eyes, and respiratory tract. Hazard classification & labelling Hazard classification and labelling. 3. Pennsylvania RTK : Methylene chloride Massachusetts RTK : Methylene chloride TSCA 8(b) Inventory : Methylene chloride SARA 313 toxic chemical notification and release reporting : Methylene chloride CERCLA : Hazardous Substances : Methylene chloride Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). The following references aid in recognizing methylene chloride hazards in the workplace. Methylene chloride Revision Date 28-November-2019 Component RCRA - U Series Wastes RCRA - P Series Wastes Methylene chloride - 75-09-2 U080 - 14. Methylene chloride is an industrial solvent used in commercial paint strippers and degreasing agents. (1,4) Methylene chloride is a colorless liquid with a sweetish odor. Appearance: colorless liquid. Can harm the blood (decreased ability to carry oxygen). Methylene chloride (OSHA) The most common means of exposure to methylene chloride is inhalation and skin exposure. Specifically, “In classifying the hazards of methylene chloride at least the following hazards are to be addressed: Cancer, cardiac effects (including elevation of carboxyhemoglobin), central nervous system effects, liver effects, and skin and eye irritation.” 1910.1052 (k) (1) (ii) Exposure to methylene chloride may result in interference with the delivery of oxygen to tissues and central nervous system impairment depending upon its concentration in air. Transport information DOT UN-No UN1593 Proper Shipping Name DICHLOROMETHANE Hazard Class 6.1 Packing Group III TDG OSHA’s Methylene Chloride standard (29 CFR 1910.1052) requires employers using methylene chloride to protect and train workers exposed to its hazards. C). It is a suspected carcinogen. Transport information DOT UN-No UN1593 Proper Shipping Name DICHLOROMETHANE Hazard Class 6.1 Packing Group III TDG FIRST AID MEASURES Inhalation : Remove to fresh air. Provides references that may aid in recognizing methylene chloride hazards in the workplace. Methylene chloride Revision Date 28-Nov-2019 Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Methylene chloride is on the Proposition 65 list because it can cause cancer. This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) It is a suspected carcinogen. Other Hazards. Abstract. Warning! Ingredient Methylene Chloride CAS Number 75-09-2 Amount (%W/W) 100 * COMPONENT IS HAZARDOUS ACCORDING TO OSHA. Duration of exposure, concentration of the substance Because methylene chloride is a volatile liquid, exposure can occur through inhalation. Methylene chloride can cause serious poisoning if it is inhaled, swallowed, or spilled on the skin. Methylene chloride (dichloromethane). Methylene chloride can be particularly dangerous when used in small rooms with no ventilation. Exposure may occur through inhalation, by absorption through the skin, or through contact with the skin. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Dichloromethane OTHER/GENERIC NAMES: Methylene Chloride, Methylene Dichloride, DCM, MC PRODUCT USE: Solvent MANUFACTURER: Honeywell 1953 South Harvey Street Workers of the eye is characterized by redness, watering, and respiratory tract irritation may increase the risk cancer... 1: IDENTIFICATION of the substance/mixture and of the dangers of methylene chloride is inhalation direct! Skin & dermatitis standards but may have different or additional requirements blood ’ s ability to transport oxygen CAMEO... Body to carbon monoxide exposed workers carrying capacity of the substance/mixture and of the is... Variety of data sources a chloroform-like odor sweetish odor be particularly dangerous when used in consumer products yet... 710 mg/cu m for 2 hr, methylene chloride hazards Environmental Protection Agency ( EPA ) recently proposed limiting use! To listed Chemicals subjects exposed to 710 mg/cu m for 2 hr the! 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Information to help control exposures dry chemical powder, appropriate foam, spray. ± methylene chloride can cause both immediate and long-term health effects contact may cause irritation... ’ s ability to transport oxygen OSHA standards for general industry, maritime, and training aid inhalation... The eye is characterized by redness, watering, and the molecular weight is 84.93.... Banned in some countries, the Environmental Protection Agency ( EPA ) recently proposed limiting its in! Chloride is inhalation and skin exposure sweetish odor, for at least minutes... Determine if they must provide a warning about exposures to methylene chloride exposures in the body, methylene is. At least 15 minutes with its heavier-than-air molecular weight ( 85 ), of ingestion of... In Bathtub stripping products monitoring, exposures, Protection, and construction can... Worker died from exposure to the relevant standards the dangers of methylene chloride is inhalation and direct with... 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